Bibb County Alabama Cities/Towns - Brent, Brierfield, Centreville (County Seat), Eoline, Green Pond, Lawley, Marvel, Randolph, West Blockton, Woodstock

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Your Ad Here Bibb County, Alabama is a county of the U.S. state of Alabama. he 2006 population estimate was 21,482. Its county seat is Centreville and it's a "prohibition" or dry county. History Its name is in honor of William W. Bibb, a Governor of Alabama.